Barcelona – Olympiacos Tip Champions League, Matchday 3 on Tuesday, 10/21/25 at 6:45 p.m.
After successfully converting the NEO.Bet bonus in the Catalan derby during the La Liga weekend, with the Blaugrana emerging victorious, the Champions League is back on the agenda on Tuesday.
My Barcelona Olympiakos tip is, as you might have guessed, a Barca win – but with a few extra goals!
Especially since Barcelona has been the most prolific goal-scoring machine in the competition since the start of the 2024/25 season, averaging 2.88 goals per game.
In the last league phase, they won their first three home games by at least three goals – a clear signal to every opponent! Only the last home game, when qualification was already certain, ended in a draw.
Barcelona vs. Olympiacos Piraeus AI predictions:
The Barcelona Olympiacos Piraeus AI prediction is similar to my own, but some of the suggestions miss out on valuable value.
The Blaugrana’s games have often been high-scoring this season: in ten of the eleven games so far, there have been more than two goals in total.
However, I don’t think it’s enough to predict a Barca win with over 2.5 goals at odds of around 1.50, as I expect the Catalans to score all the goals in Tuesday’s game – I’d rather go for a Barca win with HC -2 at significantly higher odds of around 2.40.
Predicted chance of winning:
| Barcelona win |
Draw |
Olympiakos win |
| 83.2% |
11% |
5.8% |
My personal Barcelona Olympiacos Piraeus tip is therefore firmly based on a clear home win. After all, no Greek team has ever won away in Spain in the history of this competition.
In the 21 attempts so far, the encounters with Spanish opponents have mostly ended disappointingly: 17 games were lost, while only four ended in a draw.
Goal scorer: Lamine Yamal is available at Bet365 at odds of around 1.87 and is definitely worth a try. The youngster has scored a total of four goals in his last five Champions League home games alone.
What you need to know when betting on Barcelona vs. Olympiacos Piraeus
- At least three goals were scored in 13 of FC Barcelona’s 14 Champions League games last season.
- In eleven of those 14 games, four or more goals were scored.
- Only two of the lowest-ranked UCL teams (Pafos and Kairat Almaty, 0.06 xG each) have a worse expected goals per shot value than Olympiacos (0.07 xG).
- In the last UCL clash in 2017/18, Barcelona received a -3.0 Asian handicap; Olympiacos lost 3-1 in Spain and covered the +3.0 handicap.
- Since the start of the 2024/25 season, no player in the domestic leagues has recorded more successful dribbles than Barcelona’s Lamine Yamal (182).
