PSV – Napoli Tip Champions League, Matchday 3 on Tuesday, 10/21/25 at 9:00 p.m.
Shortly before kick-off at the weekend, it was announced that both Hojlund and McTominay would not be playing in the Serie A match against FC Turin – and SSC promptly suffered a bitter 0-1 defeat.
According to my PSV Napoli tip, you would be well advised to visit a verified betting provider on Tuesday with the intention of betting on a double from the hosts plus a point.
After all, coach Antonio Conte does not attach too much importance to the Champions League anyway. In addition, his SSC has won only one of its last six European Cup games in the Netherlands.
Could there be a surprise in store, as there was during the 2012/13 season when PSV won both games against the southern Italians in the Europa League?
PSV Eindhoven vs. Napoli AI predictions:
Our PSV Eindhoven Napoli AI prediction favors a slightly more aggressive betting strategy than I do – precisely because McTominay and Hojlund could be out again for the visitors.
In addition, the path to a Dutch treble would inevitably lead to the selection 1. Goal & Win: PSV at odds of around 3.30 at Bet365.
Why? Because SSC’s last 19 competitive defeats have all been characterized by the respective opponent scoring the first goal of the game.
Predicted chance of winning:
| PSV Eindhoven win |
Draw |
Napoli win |
| 30.8% |
25.8% |
43.4% |
Furthermore, our AI also favors the betting options Both teams to score and Over 2.5 goals, whose respective PSV Eindhoven vs. Napoli odds are within a narrow range between 1.60 and 1.80.
I would even want to include both suggestions on a betting slip.
After all, the statistical conditions could hardly be better for this. Fourteen of the Dutch team’s last 17 competitive games have always met the BTS condition.
In addition, Eindhoven has only played to a nil-nil draw once in its last 18 appearances in the Champions League.
What you need to know about PSV Eindhoven vs. Napoli betting
- Both teams have scored in 14 of PSV’s last 17 competitive games.
- PSV has only kept a clean sheet once in its last 18 Champions League games.
- Napoli have conceded the first goal in each of their last 19 competitive defeats.
- Both of Napoli’s Champions League games this season have featured exactly 24 throw-ins.
